| تعداد نشریات | 284 |
| تعداد نشریات سازمان | 82 |
| تعداد شماره‌ها | 3,079 |
| تعداد مقالات | 34,341 |
| تعداد مشاهده مقاله | 47,570,258 |
| تعداد دریافت فایل اصل مقاله | 78,584,801 |
بررسی اثر نانولوله‌کربنی عامل‌دار بر خواص فیزیکی و مکانیکی نانوچندسازه چوب-پلاستیک | ||
| تحقیقات علوم چوب و کاغذ ایران | ||
| مقاله 6، دوره 38، شماره 1 - شماره پیاپی 82، فروردین 1402، صفحه 59-74 اصل مقاله (1.48 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22092/ijwpr.2022.359256.1721 | ||
| نویسندگان | ||
| محمد فارسی* 1؛ اصغر تابعی2؛ فاطمه معاشی ثانی3؛ مسعود عبادی4 | ||
| 1دانشیار، گروه علوم و صنایع چوب و کاغذ، واحد ساری، دانشگاه آزاد اسلامی، ساری، ایران | ||
| 2استادیار، گروه علوم و صنایع چوب و کاغذ، واحد آستارا، دانشگاه آزاد اسلامی، آستارا، ایران | ||
| 3مربی، گروه مهندسی صنایع، واحد ساری، دانشگاه آزاد اسلامی، ساری، ایران | ||
| 4دانشجوی دکتری علوم و مهندسی چوب و صنایع سلولزی، دانشکده منابع طبیعی و علوم دریایی، دانشگاه تربیت مدرس، نور، ایران | ||
| چکیده | ||
| هدف این پژوهش بررسی خصوصیات فیزیکی و مکانیکی نانوچندسازه چوب-پلاستیک حاصل از نانولوله کربنی خام و عامل‌دار می باشد. بدین منظور، آردچوب به مقدار ثابت 50 درصد، نانولوله‌های کربنی خام در 3 سطح 0، 1 و 2 درصد و جفت‌کننده مالئیکی در دو سطح 0 و 3 درصد در زمینه پلی‌اتیلن‌سنگین مورد استفاده قرار گرفت. همچنین از نانولوله کربنی عامل‌دار جهت تقویت کارایی نانوچندسازه در دو سطح 1 و 2 درصد به صورت جداگانه استفاده شد. مواد در مخلوط‌کن داخلی(Haake) با هم آمیخته شده و سپس نمونه‌ها توسط دستگاه پرس گرم ساخته شدند. نتایج نشان داد که با افزایش مقدار نانولوله کربنی از 0 به 2 درصد وزنی، استحکام و مدول الاستیسته کششی نمونه‌ها به ترتیب 8/58 و 6/12 درصد افزایش و جذب آب و واکشیدگی ضخامتی به میزان 5/54 و 4/19 کاهش یافت. چندسازه‌های حاوی 2 درصد وزنی نانولوله کربنی در مقایسه با چندسازه شاهد، مقاومت به ضربه بالاتری از خود نشان دادند. عامل جفت کننده مالئیکی اثر مثبتی بر کارایی نانوچندسازه‌ها داشت. خواص فیزیکی و مکانیکی نمونه‌ها با افزودن جفت کننده و نانولوله کربنی عامل‌دار بهبود محسوسی یافت. نتایج توسط میکروسکوپ الکترونی روبشی نیز مورد تأیید قرار گرفت. | ||
| کلیدواژه‌ها | ||
| جفت‌کننده مالئیکی؛ خصوصیات فیزیکی و مکانیکی؛ نانولوله کربنی خام و عامل‌دار | ||
| عنوان مقاله [English] | ||
| Investigating the effect of functionalized carbon nanotubes on physical and mechanical properties of wood-plastic nanocomposite | ||
| نویسندگان [English] | ||
| Mohammad Farsi1؛ Asghar Tabei2؛ Fatemeh Maashi sani3؛ masoud ebadi4 | ||
| 1Associate Professor, Faculty of Wood and Paper Science and Technology, Sari Branch, Islamic Azad University, Sari, Iran | ||
| 2Scientific member- Islamic Azad University, Astar Branch | ||
| 3Instructor, Faculty of Industrial Engineering, Sari Branch, Islamic Azad University, Sari, Iran | ||
| 4Ph.D. Candidate, Wood and Paper Science, Tarbiat Modares University, Noor, Iran | ||
| چکیده [English] | ||
| The purpose of this research is to investigate the physical and mechanical properties of the wood-plastic nanocomposite obtained from Raw and Functionalized carbon nanotubes (CNTs). For this purpose, wood flour at a fixed amount of 50%, Raw CNTs at three levels of 0, 1 and 2% and coupling agent at two levels of 0 and 3% were used in HDPE matrix. Also, Functionalized CNTS were used to strengthen the efficiency of nanocomposites at 1 and 2% levels separately. The materials were mixed together in an internal mixer (Haake) and then the samples were made by a hot press machine. The results showed that by increasing the amount of CNTs from 0 to 2% wt, the tensile strength and modulus of the samples increased by 58.8% and 12.6% respectively, and water absorption and thickness shrinkage decreased by 54.5% and 19.4% respectively. Composites containing 2% wt of CNTs showed higher impact resistance compared to control samples. The coupling agent had a positive effect on the performance of nanocomposites. The physical and mechanical properties of the samples were significantly improved by adding the coupling agent and Functionalized CNTs. The results were also confirmed by scanning electron microscopy. | ||
| کلیدواژه‌ها [English] | ||
| Coupling agent, Physical and mechanical properties, Raw and Functionalized CNTs | ||
| مراجع | ||
|
-Ahmadi, H., Hemmasi, A.H. and Mahdavi, S., 2015. Investigation on mechanical properties of HDPE recycled composite filled by furfural residue produced from bagasse. Iranian Journal of Wood and Paper Science Research, 30 (3): 376-387.
-Bag, D.S., Dubey, R., Zhang, N., Xie, J., Varadan, V.K., Lal, D. and Mathur, G.N., 2004. Chemical functionalization of carbon nanotubes with 3-methacryloxypropyltrimethoxysilane (3-MPTS).Smart materials and structures, 13(5): 1263-1267.
-Bai, J.B. and Allaoui, A., 2003. Effect of the length and the aggregate size of MWNTs on the improvement efficiency of the mechanical and electrical properties of nanocomposites—experimental investigation. Composites Part A: applied science and manufacturing, 34(8): 689-694.
-Bilbao-Sainz, C., Bras, J., Williams, T., Sénechal, T. and Orts, W., 2011. HPMC reinforced with different cellulose nano-particles. Carbohydrate polymers, 86(4): 1549-1557.
-Chowdhury, J.A. and Wolcott, M.P., 2007. Compatibilizer selection to improve mechanical and moisture properties of extruded wood-HDPE composites. Forest products journal, 57(9): 46-54.
-Eichhorn, S.J., Baillie, C.A., Zafeiropoulos, N., Mwaikambo, L.Y., Ansell, M.P., Dufresne, A.A., Entwistle, K.M., Herrera-Franco, P.J., Escamilla, G.C., Groom, L. and Hughes, M., 2001. Current international research into cellulosic fibres and composites. Journal of materials Science, 36(9): 2107-2131.
-Espert, A., Vilaplana, F. and Karlsson, S., 2004. Comparison of water absorption in natural cellulosic fibres from wood and one-year crops in polypropylene composites and its influence on their mechanical properties. Composites Part A: Applied science and manufacturing, 35(11): 1267-1276.
-Farsheh, A.T., Talaeipour, M., Hemmasi, A.H., Khademieslam, H. and Ghasemi, I., 2011. Investigation on the mechanical and morphological properties of foamed nanocomposites based on wood flour/PVC/multi-walled carbon nanotube. BioResources, 6(1): 841-852.
-Farsi, M., 2010. Wood-plastic composites: Influence of wood flour chemical modification on the mechanical performance. Journal of reinforced plastics and composites, 29(24): 3587-3592.
-Farsi, M. and Sani, F.M., 2014. Effects of multi-walled carbon nanotubes on the physical and mechanical properties of high-density polyethylene/wood flour nanocomposites. Journal of Thermoplastic Composite Materials, 27(8): 1139-1154.
-Ghasemi, I., Farsheh, A.T. and Masoomi, Z., 2012. Effects of multi‐walled carbon nanotube functionalization on the morphological and mechanical properties of nanocomposite foams based on poly (vinyl chloride)/(wood flour)/(multi‐walled carbon nanotubes). Journal of Vinyl and Additive Technology, 18(3): 161-167.
-Gojny, F.H., Wichmann, M.H., Fiedler, B. and Schulte, K., 2005. Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites–a comparative study. Composites science and technology, 65(15-16): 2300-2313.
-Kazemi Najafi, S., Younesi Kordkheili, H. and Nasiri Avanaki. R. 2010. Effect of sea water on compatibilizer performance in water absorption behavior of wood-polypropylene composites. Journal of Forest and Wood Products, 62(3): 169-186.
-Kim, J.K. and Pal, K., 2010. Recent advances in the processing of wood-plastic composites. Springer. Netherlands, 176p
-Kordkheili, H.Y., Farsi, M. and Rezazadeh, Z., 2013. Physical, mechanical and morphological properties of polymer composites manufactured from carbon nanotubes and wood flour. Composites Part B: Engineering, 44(1): 750-755.
-Kordkheili, H.Y., Hiziroglu, S. and Farsi, M., 2012. Some of the physical and mechanical properties of cement composites manufactured from carbon nanotubes and bagasse fiber. Materials & Design, 33: 395-398.
-Park, B.D. and Kadla, J.F., 2012. Thermal degradation kinetics of resole phenol-formaldehyde resin/multi-walled carbon nanotube/cellulose nanocomposite. Thermochimica acta, 540: 107-115.
Połeć, I., Hine, P.J., Bonner, M.J., Ward, I.M. and Barton, D.C., 2010. Die drawn wood polymer composites. I. Mechanical properties. Composites Science and Technology, 70(1): 45-52.
-Popov, V.N., 2004. Carbon nanotubes: properties and application. Materials Science and Engineering: R: Reports, 43(3): 61-102.
-Prashantha, K., Soulestin, J., Lacrampe, M.F., Claes, M., Dupin, G. and Krawczak, P., 2008. Multi-walled carbon nanotube filled polypropylene nanocomposites based on masterbatch route: Improvement of dispersion and mechanical properties through PP-g-MA addition. Express Polymer Letters, 2(10): 735-745.
-Pundhir, N., Zafar, S. and Pathak, H., 2021. Performance evaluation of HDPE/MWCNT and HDPE/kenaf composites. Journal of Thermoplastic Composite Materials, 34(10): 1315-1333.
-Salehi, S., Maghmoomi, F., Sahebian, S., Zebarjad, S.M. and Lazzeri, A., 2021. A study on the effect of carbon nanotube surface modification on mechanical and thermal properties of CNT/HDPE nanocomposite. Journal of Thermoplastic Composite Materials, 34(2): 203-220.
-Salvetat, J.P., Bonard, J.M., Thomson, N.H., Kulik, A.J., Forro, L., Benoit, W. and Zuppiroli, L., 1999. Mechanical properties of carbon nanotubes. Applied Physics A, 69(3): 255-260.
-Sanadi, A.R., Caulfield, D.F. and Jacobson, R.E., 1997. Agro-fiber thermoplastic composites. Paper and composites from agro-based resources. CRC Press, New York, USA
-Weisenberger, M.C., Grulke, E.A., Jacques, D., Rantell, A.T. and Andrewsa, R., 2003. Enhanced mechanical properties of polyacrylonitrile/multiwall carbon nanotube composite fibers. Journal of nanoscience and nanotechnology, 3(6): 535-539.
-Wu, Y., Gu, Z., Chen, M., Zhu, C. and Liao, H., 2017. Effect of functionalization of multi-walled carbon nanotube on mechanical and viscoelastic properties of polysulfide-modified epoxy nanocomposites. High Performance Polymers, 29(2): 151-160.
-Yaghoobi, H. and Fereidoon, A., 2019. Preparation and characterization of short kenaf fiber-based biocomposites reinforced with multi-walled carbon nanotubes. Composites Part B: Engineering, 162: 314-322.
-Yakobson, B.I., Brabec, C.J. and Bernholc, J., 1996. Nanomechanics of carbon tubes: instabilities beyond linear response. Physical review letters, 76(14): 2511-2514.
-Yu, M.F., Files, B.S., Arepalli, S. and Ruoff, R.S., 2000. Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties. Physical review letters, 84(24): 5552-555. | ||
|
آمار تعداد مشاهده مقاله: 530 تعداد دریافت فایل اصل مقاله: 395 |
||